Geochemical Periodic Table

Compare to chemical periodic table.
H He
Li Be B C N O F Ne
Na Mg Al Si P S Cl Ar
K Ca Sc Ti VCrMnFeCoNiCuZn GaGe AsSe Br Kr
RbSr YZrNbMoTcRuRhPdAgCd InSnSb Te I Xe
CsBa La*HfTaWReOsIrPtAuHg TlPbBiPo At Rn
Fr Ra Ac*

color code for categories

volatiles

1st series transition metals

alkali/alkali earth trace elements

semi-volatiles

high field strength elements

rare earth and related elements

major elements

noble metals

U/Th decay series elements

bold letters indicate LILE

The geochemical periodic table groups elements according to their behavior in the crust and mantle. Compare to Goldschmidt's classification.
alkali metals : alkali earth metals : halogens : inert elements : non metals : transition metals : periodic table : elemental composition of crust : Geochemical Peridiodic Table : Goldschmidt's classification : HFSE : LILE : incompatible elements : trace elements :

other : A Periodic Table of the Elements

HFSE

high field strength elements

H He
Li Be B C N O F Ne
Na Mg Al Si P S Cl Ar
K Ca Sc Ti V Cr Mn Fe Co Ni CuZn GaGe AsSe Br Kr
Rb Sr YZrNbMo TcRuRhPdAgCd InSnSb Te I Xe
Cs Ba La*HfTaWReOsIrPtAuHg TlPbBiPo At Rn
Fr Ra Ac*RfHa

The HFSE group, high field strength elements, are incompatible elements because of high ionic charge.

The incompatible HFSE with high valence are not favored for inclusion in crystal lattices despite radii that are sufficiently small for many cation sites. Their charge is so great as to require one or more energetically-unfavorable, coupled substitutions to maintain charge balance. The actinides, Th and U are sometimes included in this group because of their high ionic charge.

  • REE = rare earth elements
  • LREE = light rare earth elements (La-Sm) are in the LILE group
  • HREE = heavy rare earth elements (Eu-Lu) are in the HFSE group
  • alkali metals : alkali earth metals : halogens : inert elements : non metals : transition metals : periodic table : elemental composition of crust : Geochemical Periodic Table : Goldschmidt's classification : HFSE : LILE : incompatible elements : trace elements :

    LILE

    large-ion lithophile elements

    H He
    Li Be B C N O F Ne
    Na Mg Al Si P S Cl Ar
    K Ca Sc TiV Cr MnFeCoNiCuZn GaGe AsSe Br Kr
    Rb Sr YZrNbMoTcRuRhPdAgCdInSnSb Te I Xe
    Cs Ba La*HfTaWReOsIrPtAuHg TlPbBiPo At Rn
    Fr Raplus *actinides Th/U AcThPaUNuPu

    LILE, or large-ion lithophile elements, are high ionic radius cations that are incompatible elements because they are too large to accommodate easily into minerals crystallizing from magma.

    The major minerals in basaltic and ultramafic rocks have two kinds of cationic lattice sites:

  • Small tetrahedral sites that are most often occupied by Si and Al, and less often by Fe3+ and Ti4+.
  • Larger octahedral sites that are typically occupied by Ca, Mg, or Fe, and more rarely by Na.
  • Ionic radius and charge most govern the behavior of the alkali metals and alkali earth metals in igneous rocks. K, Rb, Cs, Sr, and Ba are often collectively termed the large-ion lithophile elements (LILE) because they have large ionic radii. The actinides, Th and U are sometimes included in this category.

    The ionic radii of the heavy alkali metals and alkali earth metals are greater than the radii of even the larger octahedral sites, so substitution of LILE at these sites causes local, energetically-unfavorable distortion of the crystal lattice. As a result, these incompatible elements tend to concentrate in the melt phase during melting or crystallization. Partial melting of the mantle, with eruption or intrusion of these partial melts atop or into the crust has resulted in enrichment of the crust in these incompatible elements over geological time.

  • REE = rare earth elements (lanthanides)
  • LREE = light rare earth elements (La-Sm) are in the LILE group
  • HREE = heavy rare earth elements (Eu-Lu) are in the HFSE group
  • alkali metals : alkali earth metals : halogens : inert elements : non metals : transition metals : periodic table : elemental composition of crust : Geochemical Periodic Table : Goldschmidt's classification : HFSE : LILE : incompatible elements : trace elements :

    Goldschmidt's classification

    Goldschmidt's classification

    H He
    Li Be B CN O F Ne
    Na Mg Al Si P S Cl Ar
    K Ca Sc Ti VCrMnFeCoNiCuZn GaGe AsSe Br Kr
    Rb Sr YZrNbMoTcRuRhPdAgCd InSnSb Te I Xe
    Cs Ba La*HfTaWReOsIrPtAuHg TlPbBiPoAtRn
    Fr Ra Ac*
    * lanthanidesLaCePrNdPmSmEuGdTbDyHoErTmYbLu
    *actinidesAcThPaUNuPu

    lithophile

    siderophile

    chalcophile

    atmophile

    lithophile-siderophile

    siderophile-chalcophile

    Goldschmidt classified elements according to their affinities for gaseous and liquid phases:

    Atmophile elements concentrate in the atmosphere and hydrosphere because they are volatile.

    Lithophile elements concentrate in the crust and mantle because of their affinity for silicate phases.

    Siderophile elements are depleted in the silicate portion of the Earth and are presumably concentrated in the core because they display an affinity for a metallic liquid phase.

    Chalcophile elements are also depleted in the silicate earth and may be concentrated in the core by virtue of their affinity for a sulfide liquid phase.

  • REE = rare earth elements (lanthanides)
  • LREE = light rare earth elements (La-Sm) are in the LILE group
  • HREE = heavy rare earth elements (Eu-Lu) are in the HFSE group
  • alkali metals : alkali earth metals : halogens : inert elements : metals : non metals : transition metals : periodic table : elemental composition of crust : HFSE : LILE : incompatible elements :
    other : A Periodic Table of the Elements

    lanthanides actinides

    Lanthanides and Actinides

    lanthanides La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
    actinides Ac Th Pa U Nu Pu Am Cm Bk Cf Es Fm Md No Lr

    rock forming minerals

  • REE = rare earth elements (lanthanides)
  • LREE = light rare earth elements (La-Sm) are in the LILE group
  • HREE = heavy rare earth elements (Eu-Lu) are in the HFSE group
  • The lanthanides (lanthanoids) have atomic numbers from 57 through to 71.

    The geochemical behaviors of lanthanides are a regular function of ionic radius and atomic number. In the lanthanide contraction, the ionic radii of the lanthanides decreases through the series. This relationship between geochemical activity and ionic radius results in variations in the abundances of lanthanides that can be used to trace natural materials through physical and chemical processes.

    The lanthanides are divided into light- and heavy-lanthanide enriched minerals because of the lanthanide contraction. The light lanthanides are more abundant in the Earth's crust, whereas the heavy lanthanides are more abundant in the Earth's mantle. As a result, large rich orebodies are much more likely enriched in the light than the heavy lanthanides. (The lanthanides obey the Oddo-Harkins rule, according to which odd-numbered elements are less abundant than their even-numbered neighbors.) Also useful to geochemists, 147Sm and 176Lu are radioactive isotopes with long half-lives that can be employed in radiometric dating.

    The lanthanides, except for Ce and Eu, occur as trivalent cations in nature. The lanthanides are often referred to in geochemistry by the trivial name, "rare earths". REE is sometimes used to describe all the lanthanides except Pm, together with Sc and Y.

    The term "rare earths" came into use because the lanthanides were isolated from uncommon oxide-type minerals. The term "earths" is an obsolete term that described the water-insoluble strongly basic oxides of electropositive metals that late 18th century technology was incapable of smelting to metal. Although these elements are found only in trace amounts compared to the common rock forming minerals, they are not rare: Nd is more abundant than gold, and even the least common naturally-occurring lanthanide (Tm) is more abundant than iodine.

    Here's a mnemonic for the lanthanide series: Ladies Can't Put Nickels Properly into Slot-machines. Every Girl Tries Daily, However, Every Time You Look.

    Connected binary-phase diagram (temperature vs. composition) of the actinides. Such diagrams demonstrate the transition from typical metallic behavior at thorium to the enormous complexity at plutonium and back to typical metallic behavior past americium.The actinides (actinoids) have atomic numbers from 89 through to 103.

    Only thorium and uranium are found in significant quantities in the Earth's crust. All actinides are radioactive and the members exhibit a wider range of oxidation states than do the lanthanide. So, the actinides display less similarity in their chemical properties than do the lanthanides.

    The image above left represents a connected binary-phase diagram (temperature vs. composition) for the actinides. The actinides make a transition from typical metallic behavior at thorium to the enormous complexity at plutonium and back to typical metallic behavior past americium. [source]

    alkali metals : alkali earth metals : halogens : inert elements : non metals : transition metals : periodic table : elemental composition of crust : Goldschmidt's classification : HFSE : LILE : incompatible elements : trace elements :

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    non-metals

    H He
    Li Be BCNO F Ne
    Na Mg Al SiPS Cl Ar
    K Ca Sc TiV Cr MnFeCoNiCuZn GaGe AsSe Br Kr
    Rb Sr YZrNbMoTcRuRhPdAgCd InSnSb Te I Xe
    Cs Ba La*HfTaWReOsIrPtAuHg TlPbBiPo At Rn
    Fr Ra Ac*RfHa
    alkali metals : alkali earth metals : halogens : inert elements : metals : non metals : transition metals : periodic table : elemental composition of crust :

    transition metals

    H He
    Li Be B C N O F Ne
    Na Mg Al Si P S Cl Ar
    K Ca ScTiVCrMnFeCoNiCuZn GaGe AsSe Br Kr
    Rb Sr YZrNbMo TcRuRhPdAgCd InSnSb Te I Xe
    Cs Ba La*HfTaWReOsIrPtAuHg TlPbBiPo At Rn
    Fr Ra Ac*RfHa
    alkali metals : alkali earth metals : halogens : inert elements : metals : non metals : transition metals : periodic table : elemental composition of crust :

    alkali metals

    H He
    Li Be B C N O F Ne
    Na Mg Al Si P S Cl Ar
    K Ca Sc TiV Cr MnFeCoNiCuZn GaGe AsSe Br Kr
    Rb Sr YZrNbMoTcRuRhPdAgCdInSnSb Te I Xe
    Cs Ba La*HfTaWReOsIrPtAuHg TlPbBiPo At Rn
    Fr Ra Ac*RfHa
    The major minerals in basaltic and ultramafic rocks have two kinds of cationic lattice sites:
  • Small tetrahedral sites that are most often occupied by Si and Al, and less often by Fe3+ and Ti4+.
  • Larger octahedral sites that are typically occupied by Ca, Mg, or Fe, and more rarely by Na.

  • Ionic radius and charge most govern the behavior of the alkali metals and alkali earth metals in igneous rocks. K, Rb, Cs, Sr, and Ba are often collectively termed the large-ion lithophile elements (LILE) because they have large ionic radii. The actinides, Th and U are sometimes included in this category.

    The ionic radii of the heavy alkali metals and alkali earth metals are greater than the radii of even the larger octahedral sites, so substitution of LILE at these sites causes local, energetically-unfavorable distortion of the crystal lattice. As a result, these incompatible elements tend to concentrate in the melt phase during melting or crystallization. Partial melting of the mantle, with eruption or intrusion of these partial melts atop or into the crust has resulted in enrichment of the crust in these incompatible elements over geological time.

    alkali metals : alkali earth metals : halogens : inert elements : non metals : transition metals : periodic table : elemental composition of crust : Goldschmidt's classification : HFSE : LILE : incompatible elements : trace elements :

    alkali earth metals

    H He
    Li Be B C N O F Ne
    Na Mg Al Si P S Cl Ar
    K Ca Sc TiV Cr MnFeCoNiCuZn GaGe AsSe Br Kr
    Rb Sr YZrNbMoTcRuRhPdAgCd InSnSb Te I Xe
    Cs Ba La*HfTaWReOsIrPtAuHg TlPbBiPo At Rn
    Fr Ra Ac*RfHa
    The major minerals in basaltic and ultramafic rocks have two kinds of cationic lattice sites:
  • Small tetrahedral sites that are most often occupied by Si and Al, and less often by Fe3+ and Ti4+.
  • Larger octahedral sites that are typically occupied by Ca, Mg, or Fe, and more rarely by Na.
  • Ionic radius and charge most govern the behavior of the alkali metals and alkali earth metals in igneous rocks. K, Rb, Cs, Sr, and Ba are often collectively termed the large-ion lithophile elements (LILE) because they have large ionic radii. The actinides, Th and U are sometimes included in this category.

    The ionic radii of the heavy alkali metals and alkali earth metals are greater than the radii of even the larger octahedral sites, so substitution of LILE at these sites causes local, energetically-unfavorable distortion of the crystal lattice. As a result, these incompatible elements tend to concentrate in the melt phase during melting or crystallization. Partial melting of the mantle, with eruption or intrusion of these partial melts atop or into the crust has resulted in enrichment of the crust in these incompatible elements over geological time.

    alkali metals : alkali earth metals : halogens : inert elements : non metals : transition metals : periodic table : elemental composition of crust : Goldschmidt's classification : HFSE : LILE : incompatible elements : trace elements :

    halogens

    H He
    Li Be BCNO F Ne
    Na Mg Al Si P S Cl Ar
    KCa Sc TiV Cr MnFeCoNiCuZn GaGe AsSe Br Kr
    Rb SrYZrNbMoTcRuRhPdAgCd InSnSb Te I Xe
    Cs Ba La*HfTaWReOsIrPtAuHg TlPbBiPo At Rn
    Fr Ra Ac*RfHa
    alkali metals : alkali earth metals : halogens : inert elements : metals : non metals : transition metals : periodic table : elemental composition of crust :

    inert elements

    H He
    Li Be BCNO F Ne
    Na Mg Al Si P S ClAr
    K Ca Sc TiV Cr MnFeCoNiCuZn GaGe AsSe Br Kr
    Rb Sr YZrNbMoTcRuRhPdAgCd InSnSb Te I Xe
    Cs Ba La*HfTaWReOsIrPtAuHg TlPbBiPo At Rn
    Fr Ra Ac*RfHa
    alkali metals : alkali earth metals : halogens : inert elements : metals : non metals : transition metals : periodic table : elemental composition of crust :

    metals

    H He
    Li Be BCNO F Ne
    Na Mg Al Si P S ClAr
    K Ca Sc TiV Cr MnFeCoNiCuZn GaGe AsSe BrKr
    Rb Sr YZrNbMoTcRuRhPdAgCd InSnSb Te I Xe
    Cs Ba La*HfTaWReOsIrPtAuHg TlPbBiPo At Rn
    Fr Ra Ac*RfHa
    alkali metals : alkali earth metals : halogens : inert elements : metals : non metals : transition metals : periodic table : elemental composition of crust :

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    elemental composition of crust

    H He
    Li Be B C N O F Ne
    Na Mg Al Si P S Cl Ar
    K Ca Sc TiV Cr MnFeCoNiCuZn GaGe AsSe Br Kr
    Rb Sr YZrNbMoTcRuRhPdAgCd InSnSb Te I Xe
    Cs Ba La*HfTaWReOsIrPtAuHg TlPbBiPo At Rn
    Fr Ra Ac*RfHa
    alkali metals : alkali earth metals : halogens : inert elements : metals : non metals : transition metals : periodic table :

    element

    radius

    ion (nm)

    composition

    crustal rocks

    composition

    continental crust

    Oxygen (O)

    O 2- 1.40

    46.2%

    45.2%

    Silicon (Si)

    Si4+ 0.41

    27.7%

    27.2%

    Aluminum (Al)

    Al3+ 0.50

    8.1%

    8.00%

    Iron (Fe)

    Fe3+ 0.76

    5.0%

    5.8%

    Calcium (Ca)

    Ca2+ 0.99

    3.6%

    5.06%

    Sodium (Na)

    Na+ 0.95

    2.8%

    2.32%

    Potassium (K)

    K+ 1.33

    2.5%

    1.68%

    Magnesium (Mg)

    Mg2+ 0.65

    2.1%

    2.77%

    Titanium (Ti)

    0.86%

    Hydrogen (H)

    0.14%

    Manganese (Mn)

    0.10%

    Phosphorus (P)

    0.10%

    Other elements

    1.7%

    0.77%

    Total

    100%

    100%

    Pb

    Pb2+ 1.20

    Li

    Li+ 0.60

    C

    C4+ 0.15

    0.03%

    S

    S2- 1.84

    0.05%

    Cl

    Cl- 1.81

    F

    F- 1.36

    H

    0.10%

    after K.K. Turekian, 1969

    periodic table

    chemical periodic table of elements

    H He
    Li Be B C N O F Ne
    Na Mg Al Si P S Cl Ar
    K Ca Sc Ti VCrMnFeCoNiCuZn GaGe AsSe Br Kr
    RbSr YZrNbMoTcRuRhPdAgCd InSnSb Te I Xe
    CsBa La*HfTaWReOsIrPtAuHg TlPbBiPo At Rn
    Fr Ra Ac*RfHa106107108109110

    color code for chemical periodic table

    alkali metals

    alkali earth metals

    halogens

    inert elements

    non metals

    transition metals

    HFSE

    metals

    LILE

    alkali metals : alkali earth metals : halogens : inert elements : metals : non metals : transition metals : periodic table : elemental composition of crust :

    other : A Periodic Table of the Elements