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garnets
X3Y2(SiO4)3 |
images - click to enlarge - top, garnet crystals; second, andradite; third, espessartite; fourth, uvarovite; fifth, almandine in gneissic rock; bottom, garnet structure      
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Minerals of the garnet group are nesosilicates in the isometric system that display either dodecahedral or trapezohedral crystal habits. Garnets are red, orange, yellow, green, blue, purple, brown, black, pink or colorless gemstones. There are six common varieties of garnets – pyrope, almandine, spessartite, grossular, uvarovite and andradite. Garnets are key indicator minerals used in geothermobarometric determination of the genesis of many igneous and metamorphic rocks. Garnets are relatively resistant to alteration, and diffusion of elements is relatively slow in garnet. Therefore, individual garnets commonly preserve compositional zonations that can be employed for interpretion of temperature-time histories of rock. When garnet grains lack compositional zonation, they are interpreted as having been homogenized by diffusion. Garnets are also employed to definine metamorphic facies of rocks. For example, eclogite has basaltic composition, but chiefly comprises garnet and omphacite. Pyrope-rich garnet is restricted to relatively high-pressure metamorphic rocks, such as those in the lower crust and in the Earth's mantle. Peridotite may contain plagioclase, or aluminum-rich spinel, or pyrope-rich garnet, and the presence of each of the three minerals defines a pressure-temperature range in which the mineral could equilibrate with olivine plus pyroxene: the three are listed in order of increasing pressure for stability of the peridotite mineral assemblage. Hence, garnet peridotite must have been formed at great depth in the earth. Xenoliths of garnet peridotite have been carried up from depths of 100 km and greater by kimberlite, and garnets from such disaggegated xenoliths are used as a kimberlite indicator minerals in diamond prospecting. At depths of about 300 to 400 km and greater, a pyroxene component is dissolved in garnet, by the substitution of (Mg,Fe) plus Si for 2Al in the octahedral (Y) site in the garnet structure, creating unusually silica-rich garnets that have solid solution towards majorite. Such silica-rich garnets have been identified as inclusions within diamonds. Garnets are found in mica schists (almandite); mantle derived rocks, such as peridotites and eclogites (pyrope is indicator mineral for high pressure metamorphism); granite pegmatite and grade metamorphic phyllites (spessartite ); deep-seated igneous rocks like syenite as well as serpentines, schists, and crystalline limestone (andradite); contact metamorphosed limestones with vesuvianite, diopside, wollastonite and wernerite (grossular); crystalline marbles and schists associated with chromite in peridotite, serpentinite, and kimberlites (uvarovite). |